Tyres – loss of carbon atoms

Question: How many atoms of carbon wear off a tyre per rotation of
the tyre?
Answer:
This will be a very rough estimate but it is a
fascinating question.
The wear will depend on how the car is driven, road conditions,
braking, make of tyre etc. but roughly car tyres wear down by about 6 mm over 20 000 miles
of driving.
My car tyres have a radius of about 0.6 m and a width of 0.15 m and so
for 0.006 m (6 mm) of rubber to wear off them they must have lost 0.0017 cubic metres of
rubber.
The density of rubber is a little less than water (to test this will a car tyre
float in water? If yes then its density is less than water). Lets say 950 kg/cubic
metre.
So the mass of rubber worn away = 0.0017x950 = 1.62 kg
Each
molecule of rubber (assuming that the tyres are pure rubber) is a chain molecule of many
units, each unit is 5 carbons and 8 hydrogens. Therefore 60/68 of the mass is
carbon.
Therefore 1.6x60/68 = 1.4118 kg is carbon.
The mass of a carbon
atom is 12x1.6x10
-27 kg = 1.92x10
-26 kg
So the number of carbon
atoms rubbed off is 1.4118/1.92x10
-26 = 7.35x10
25 atoms
The
circumference of the tyre is 1.9 m and therefore in travelling 20 000 miles (or 32 000 km = 32
000 000) they will have rotated 32 000 000/1.9 = almost 17 million times!
Therefore
in one rotation the tyre will lose 7.35x10
25/17 million = 4.3x10
18 carbon
atoms.
Roughly 4 million million million carbon atoms will be rubbed off every
rotation!
This is a very rough estimate that all depends on my guess as to molecular
weight and structure of the rubber used in car tyres. Actually it is even worse because tyres
are made of 28% carbon black, 27% synthetic polymer, 14% natural rubber, 10% wire, 10%
oil, and 11% other materials.